Characterization of PtSn nanoparticles in KL zeolite and n-hexane aromatization activity

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Bimetallic nanoparticles of Pt and Sn have been prepared with an ion exchange of Sn2+ ions into KL zeolite containing 1-nm Pt nanoparticles. Incorporation of Sn does not cause a blockage for xenon adsorption. The results of data analysis of X-ray absorption. ne structure show that the obtained particle size does not increase significantly. The microstructure of the PtSn nanoparticles seems to be Pt core covered with Sn. The obtained PtSn nanoparticles show a high selectivity to benzene with a comparable turnover rate for n-hexane aromatization.
Publisher
SPRINGER
Issue Date
2004-08
Language
English
Article Type
Article
Keywords

X-RAY-ABSORPTION; PLATINUM-TIN CATALYSTS; FINE-STRUCTURE; SUPPORTED PLATINUM; NAY ZEOLITE; XE-129 NMR; ADSORPTION; EXAFS; ATOMS

Citation

CATALYSIS LETTERS, v.97, no.1-2, pp.71 - 75

ISSN
1011-372X
DOI
10.1023/B:CATL.0000034290.27465.f9
URI
http://hdl.handle.net/10203/12485
Appears in Collection
CH-Journal Papers(저널논문)
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