Chalcogenide Chemistry in Ionic Liquids: Nonlinear Optical Wave-Mixing Properties of the Double-Cubane Compound [Sb7S8Br2](AlCl4)(3)
The new cation [Sb7S8Br2](3+) has a double-cubane structure and forms as the [AlCl4](-) salt from the ionic liquid EMIMBr-AlCl3 (EMIM = 1-ethyl-3-methylimidazolium) at 165 degrees C. The compound is noncentrosymmetric with space group P2(1)2(1)2(1) and exhibits second-harmonic and difference-frequency nonlinear optical response across a wide range of the visible and near-infrared regions.
- Publisher
- AMER CHEMICAL SOC
- Issue Date
- 2009-07
- Language
- English
- Article Type
- Article
- Keywords
OPEN-FRAMEWORK CHALCOGENIDES; GENERATION; CS; NANORODS; FIGURE; LAYERS; LIGHT; MERIT; RB
- Citation
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, v.131, no.29, pp.9896 - 9896
- ISSN
- 0002-7863
- Appears in Collection
- NT-Journal Papers(저널논문)
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