Intramolecular Oxidative Diamination and Aminohydroxylation of Olefins under Metal-Free Conditions

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A metal-free procedure that is simple to operate and convenient to handle was developed for the facile intramolecular oxidative diamination of olefins using an iodobenzene diacetate oxidant and a halide additive to furnish bisindolines at room temperature. The present reaction is featured by mild conditions, a broad substrate scope, and excellent functional group tolerance. The same protocol was successfully extended to the aminohydroxylation.
Publisher
AMER CHEMICAL SOC
Issue Date
2012-03
Language
English
Article Type
Article
Keywords

N BOND FORMATION; ACTIVATED METHYLENE-COMPOUNDS; C-H BONDS; CONJUGATED DIENES; STEREOSELECTIVE-SYNTHESIS; MECHANISTIC PATHWAYS; HYPERVALENT IODINE; DIRECT AMINATION; ALKENES; CYCLIZATION

Citation

ORGANIC LETTERS, v.14, no.6, pp.1424 - 1427

ISSN
1523-7060
DOI
10.1021/ol300166q
URI
http://hdl.handle.net/10203/102744
Appears in Collection
CH-Journal Papers(저널논문)
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