Noninvasive functionalization of polymers of intrinsic microporosity for enhanced CO2 capture

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Modifying sorbents for the purpose of improving carbon dioxide capture often results in the loss of surface area or accessible pores, or both. We report the first noninvasive functionalization of the polymers of intrinsic microporosity (PIMs) where inclusion of the amidoxime functionality in PIM-1 increases carbon dioxide capacity up to 17% and micropore surface area by 20% without losing its film forming ability.
Publisher
ROYAL SOC CHEMISTRY
Issue Date
2012-08
Language
English
Article Type
Article
Keywords

GAS-TRANSPORT PROPERTIES; CARBON-DIOXIDE; ORGANIC FRAMEWORKS; SURFACE-AREA; NETWORKS; SEPARATIONS; ADSORPTION; AMIDOXIMES; CHEMISTRY; CATALYSIS

Citation

CHEMICAL COMMUNICATIONS, v.48, no.80, pp.9989 - 9991

ISSN
1359-7345
DOI
10.1039/c2cc35392j
URI
http://hdl.handle.net/10203/102350
Appears in Collection
EEW-Journal Papers(저널논문)
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