We perform first-principles density functional calculations to study the electronic structure of Ni/HfO2 and Ni/SiO2 interfaces and the effect of O-vacancy (V-O) defects on the Schottky barrier height and the effective work function. We generate two interface models in which Ni is placed on O-terminated HfO2 (1 0 0) and a-quartz (1 0 0) surfaces. As the concentration of V-O defects at the interface increases, the p-type Schottky barrier height tends to increase in the Ni/HfO2 interface, due to the reduction of interface dipoles, whereas it is less affected in the Ni/SiO2 interface. (C) 2011 Elsevier B.V. All rights reserved.